OXIDATION OF ANTHRACENE DERIVED FROM COAL TAR: MECHANISMS AND APPLICATIONS
Keywords:
Anthracene, oxidation, coal tar, polycyclic aromatic hydrocarbons (PAHs), anthraquinone, catalysis, environmental degradation.Abstract
The oxidation of anthracene, a polycyclic aromatic hydrocarbon (PAH) derived from coal tar, has garnered significant attention due to its potential applications in the synthesis of valuable chemicals and materials. This article explores the mechanisms of anthracene oxidation, focusing on both chemical and enzymatic pathways. The discussion includes the role of catalysts, reaction conditions, and the formation of oxidation products such as anthraquinone, which is widely used in the dye and pharmaceutical industries. The environmental implications of anthracene oxidation are also addressed, highlighting its relevance in the degradation of PAHs in polluted ecosystems. This review aims to provide a comprehensive understanding of anthracene oxidation and its industrial and environmental significance.
References
1. Harvey, R. G. (1997). Polycyclic Aromatic Hydrocarbons: Chemistry and Carcinogenicity. Cambridge University Press.
2. Cerniglia, C. E. (1992). Biodegradation of polycyclic aromatic hydrocarbons. Biodegradation, 3(2-3), 351-368.
3. Baird, W. M., & Ralston, S. L. (1997). Carcinogenic polycyclic aromatic hydrocarbons. In Comprehensive Toxicology (Vol. 12, pp. 171-200). Elsevier.
4. Hudlicky, M. (1990). Oxidations in Organic Chemistry. American Chemical Society.
5. Singh, P., & Cameotra, S. S. (2004). Potential applications of microbial surfactants in biomedical sciences. Trends in Biotechnology, 22(3), 142-146.
6. Arey, J., & Atkinson, R. (2003). Photochemical reactions of PAHs in the atmosphere. Journal of Photochemistry and Photobiology A: Chemistry, 158(1), 63-71.
7. Samanta, S. K., Singh, O. V., & Jain, R. K. (2002). Polycyclic aromatic hydrocarbons: environmental pollution and bioremediation. Trends in Biotechnology, 20(6), 243-248.